This follows an approach from FA Chairman David Bernstein to West Bromwich Albion Chairman Jeremy Peace.
David Bernstein said: "I'm grateful to Jeremy and all at West Bromwich Albion for their co-operation in allowing us to approach Roy, who I have since spoken with.
"Roy is the only manager we have approached and we remain on course to make an appointment within the timescale we set-out soon after Fabio Capello's departure.
"Further conversations will now take place with Roy and my Club England colleagues before any further announcements can be made."